Sigma-Aldrich

Chloroform-D 99.8 Atom % D 0.5 Wt. % Silver Foil 03 % (V/V) TMS 250 grams

Part Number:
MIL-530735-250G
Lead Time:
2-4 weeks
Shipping:
FREE SHIPPING on most orders over $50*
Quantity:
each
Size:
250 grams
Style:
chemical
DOT Rated:
HazMat Transport Fee Required
Price: $292.90

Bulk discount rates

Automatically save when you buy in bulk.

Buy 6 - 11 and get 10% off
Buy 12 or above and get 15% off

Description

Chloroform-D ≥99.8 Atom % D 0.5 Wt. % Silver Foil 0.03 % (V/V) TMS 250 Gram

Synonym: Deuterochloroform

  • CAS Number 865-49-6
  • Linear Formula CDCl3
  • Molecular Weight 120.38
  • Beilstein/REAXYS Number 1697633
  • EC Number 212-742-4
  • MDL number MFCD00000827
  • PubChem Substance ID 24877772
  • NACRES NA.21
isotopic purity ≥99.8 atom % D
assay ≥99% (CP)
contains 0.5 wt. % silver foil as stabilizer
  0.03 % (v/v) TMS
impurities ≤0.0100% waterwater
refractive index n20/D 1.444 (lit.)
bp 60.9 °C (lit.)
mp −64 °C (lit.)
density 1.500 g/mL at 25 °C (lit.)
mass shift M+1
SMILES string [2H]C(Cl)(Cl)Cl
InChI 1S/CHCl3/c2-1(3)4/h1H/i1D
InChI key HEDRZPFGACZZDS-MICDWDOJSA-N

General description

Chloroform-d (deuterochloroform, CDCl3) is a deuterated NMR solvent containing 0.03% (v/v) TMS (tetramethylsilane) and 0.5wt.% silver foil as stabilizer. It isuseful in NMR-based research and analyses. It may be synthesized by reacting trichloroacetophenone and sodium deuteroxide. The influence of the number of pulses on its multiphoton decomposition (MPD) has been studied. Infrared spectral studies of C-D stretching and bending motions of CDCl3 in different solvents have been investigated. The effect of chloroform-d on the interaction of water with activated carbons has been analyzed. The dependence of molecular reorientation of deuterated chloroform on pressure and temperature has been studied by Raman spectroscopy.

Application

Chloroform-d may be used in the synthesis of dichlorofluoromethane-d.

GHS07GHS06, GHS08

Signal word Danger
Hazard statements H302-H315-H319-H331-H351-H361d-H372
Precautionary statements P260-P280-P301 + P312 + P330-P304 + P340 + P312-P305 + P351 + P338-P403 + P233
Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US)
RIDADR UN 1888 6.1 / PGIII
WGK Germany 3

Documents 

Warnings

Note: These chemicals are for research & laboratory use only. Your order will not be processed if you do not work for, and ship to, a registered laboratory or research facility. Not for topical applications. An official Declaration of Use form may be required.

Most chemicals cannot be expedited.

This item has a Haz-Mat shipping fee built into the price. Fee is applicable only to the first item purchased. Additional HazMat items will be discounted automatically in the shopping cart. HazMat items always require special DOT handling and in rare cases may incur additional fees not levied prior to checkout. Request a quote for the most accurate pricing.

WARNING: This product can expose you to chemicals which are known to the State of California to cause cancer and reproductive harm. Prop 65 Warning

Please note: This product is not returnable.

View AllClose

0 Reviews

View AllClose
MPN:
530735-250G