Sigma-Aldrich

Potassium Permanganate ACS Reagent, 99% 2.5 kg

Part Number:
MIL-223468-25KG
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7-14 days
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Size:
2.5 kg
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chemical
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Price: $444.34

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Description

Potassium Permanganate ACS Reagent ≥99.0% 2.5 Kg

  • CAS Number 7722-64-7
  • Empirical Formula (Hill Notation) KMnO4
  • Molecular Weight 158.03
  • EC Number 231-760-3
  • MDL number MFCD00011364
  • PubChem Substance ID 329752309
  • NACRES NA.21
Grade ACS reagent
InChI Key VZJVWSHVAAUDKD-UHFFFAOYSA-N
Assay ≥99.0%
Impurities ≤0.005% N compounds
≤0.2% insolubles
anion traces

chloride, chlorate (as Cl-): ≤0.005%
sulfate (SO42-): ≤0.02%

General description


Potassium permanganate (KMnO4) exhibits strong oxidizing properties. KMnO4 on dissolution in benzene and on complexation with dicyclohexyl-18-crown-6, affords a useful oxidizing reagent. This Reagent participates as an oxidant for the oxidation of olefins, alcohols, aldehydes and alkyl benzenes under mild conditions.

Potassium permanganate, a dark violet colored crystalline solid, is a strong oxidizing agent for a wide range of organic compounds. It is commonly used as a disinfectant to treat external infections in aquaculture. Corncobs pretreated with alkaline potassium permanganate solution showed high carbohydrate recovery due to the increased enzymatic hydrolysis of lignocellulose. The acidic potassium permanganate acts a chemiluminescence Reagent for the determination of organic compounds.

Application

Layered MnO2 with very promising characteristics for battery applications is produced by thermal decomposition of KMnO4.

Potassium permanganate may be employed as an oxidizing agent in the synthesis of the following:
sulfonal (2,2-bisethylsulfonyyl)propane
cinchomeronic acid (pyridine-3,4-dicarboxylic acid)
isonicotinic acid (pyridine-4-carboxylic acid)
manganese(IV) sulfate
Potassium permanganate may be used as an oxidant for the conversion of aromatic aldehydes to corresponding amides in liquid ammonia.

Suitable for heterogeneous oxidations.

Safety Information

GHS03GHS05GHS07GHS09 GHS03,GHS05,GHS07,GHS09

Signal word Danger
Hazard statements H272-H302-H314-H410
Precautionary statements P210-P220-P260-P273-P280-P303 + P361 + P353-P304 + P340 + P310-P305 + P351 + P338 + P310-P370 + P378-P391
RIDADR UN 1490 5.1 / PGII
WGK Germany 3
RTECS SD6475000

Documents 

Safety Data Sheet

Warnings

Note: These chemicals are for research & laboratory use only. Your order will not be processed if you do not work for, and ship to, a registered laboratory or research facility. Not for topical applications. An official Declaration of Use form may be required.

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WARNING: This product can expose you to chemicals which are known to the State of California to cause cancer and reproductive harm. Prop 65 Warning

Please note: This product is not returnable.

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MPN:
223468-2.5KG