Sigma-Aldrich
Tin(II) Chloride Reagent, Grade 98% 2 kg
- Part Number:
- MIL-208256-2KG
- Lead Time:
- 7-14 days
- Shipping:
- FREE SHIPPING on most orders over $50*
- Quantity:
- each
- Size:
- 2 kg
- Style:
- chemical
- DOT Rated:
- HazMat Transport Fee Required
Bulk discount rates
Automatically save when you buy in bulk.
Buy 6 - 11 | and get 10% off |
Buy 12 or above | and get 15% off |
Description
Tin(II) Chloride Reagent Grade 98% 2 Kg
Synonym: Stannous chloride
- CAS Number 7772-99-8
- Linear Formula SnCl2
- Molecular Weight 189.62
- EC Number 231-868-0
- MDL number MFCD00011241
- PubChem Substance ID 329752041
Grade | reagent grade |
InChI Key | AXZWODMDQAVCJE-UHFFFAOYSA-L |
Assay | 98% |
bp | 652°C (lit.) |
mp | 246°C (lit.) |
General description
SnCl2 dihydrate reacts with acetic anhydride to yield anhydrous SnCl2. SnCl2 exhibits reducing properties in acidic media. SnCl2 shows superior catalytic action in its molten state. It is a promising raw material for the chemical vapor deposition (CVD) of semiconducting layers. SnCl2 participates in the reduction of aromatic nitro compounds, nitriles, cyanosilyl ethers and organic azides.
Application
Tin(II) chloride (SnCl2) has been used as a starting material to evaluate the thermal behavior of SnCl2 on heating at the rate of 5°Cmin-1 in air. The product undergoes phase transformation on heating at rate of 5°C min-1 in air, it involves an incomplete evaporation followed by oxidation forming SnO2 nanoparticles. SnCl2 has also been used for the fabrication of Sn-containing carbon nano-structures.
Tin(II) chloride may be used:
To catalyze the addition of diazo sulfones, diazo phosphine oxides and diazo phosphonates to aldehydes to form β-keto sulfones, β-keto phosphine oxides and β-keto phosphonates, respectively.
Along with trityl chloride, to catalyze the aldol reaction of silyl enol ethers with acetals or aldehydes and the Michael reaction of silyl enol ethers with α,β-unsaturated ketones.
As a promoter in the allylic amination of allylic alcohols with amines in the presence of palladium catalyst.
Safety InformationGHS05, GHS07, GHS08, GHS09
Signal word Danger
Hazard statements H302 + H332-H314-H317-H373-H410
Precautionary statements P260-P273-P280-P303 + P361 + P353-P304 + P340 + P310-P305 + P351 + P338-P391
RIDADR UN3260 - class 8 - PG 2 - EHS - Corrosive solid, acidic, inorganic, n.o.s., HI: all
WGK Germany 3
RTECS XP8700000
Documents
Warnings
Note: These chemicals are for research & laboratory use only. Your order will not be processed if you do not work for, and ship to, a registered laboratory or research facility. Not for topical applications. An official Declaration of Use form may be required.
Most chemicals cannot be expedited.
This item has a Haz-Mat shipping fee built into the price. Fee is applicable only to the first item purchased. Additional HazMat items will be discounted automatically in the shopping cart. HazMat items always require special DOT handling and in rare cases may incur additional fees not levied prior to checkout. Request a quote for the most accurate pricing.
WARNING: This product can expose you to chemicals which are known to the State of California to cause cancer and reproductive harm. Prop 65 Warning
Please note: This product is not returnable.