Sigma-Aldrich

Tetrahydrofuran Contains 250 ppm BHT Puriss. 99.9% 1 Liter

Part Number:
MIL-87368-1L
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2-4 weeks
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Size:
1 liter / 32 ounce
Style:
chemical
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Price: $339.00

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Description

Tetrahydrofuran Contains 250 ppm BHT Puriss. ≥99.9% 1 Liter

Synonym: Butylene oxide, Oxolane, Tetramethylene oxide

  • CAS Number 109-99-9
  • Empirical Formula (Hill Notation) C4H8O
  • Molecular Weight 72.11
  • Beilstein/REAXYS Number 102391
  • EC Number 203-726-8
  • MDL number MFCD00005356
  • PubChem Substance ID 329769580
Quality Level 200
grade ACS reagent
  Reag. Ph. Eur.
vapor density 2.5 (vs air)
vapor pressure 114 mmHg ( 15 °C)
  143 mmHg ( 20 °C)
grade puriss. p.a.
assay ≥99.9%
autoignition temp. 610 °F
contains 250 ppm BHT as inhibitor
  ~0.025% 2,6-di-tert-butyl-4-methylphenol as stabilizer
expl. lim. 1.8-11.8 %
impurities ≤0.001% free acid (as CH3COOH)
  ≤0.005% peroxides (as H2O2)
  ≤0.05% water
evapn. residue ≤0.001%
refractive index n20/D 1.407 (lit.)
  n20/D 1.407
bp 65-67 °C (lit.)
mp −108 °C (lit.)
density 0.887 g/mL at 20 °C
  0.889 g/mL at 25 °C (lit.)
cation traces Al: ≤0.5 mg/kg
  B: ≤0.02 mg/kg
  Ba: ≤0.1 mg/kg
  Bi: ≤0.1 mg/kg
  Ca: ≤0.5 mg/kg
  Cd: ≤0.05 mg/kg
  Co: ≤0.02 mg/kg
  Cr: ≤0.02 mg/kg
  Cu: ≤0.02 mg/kg
  Fe: ≤0.1 mg/kg
  K: ≤0.5 mg/kg
  Li: ≤0.1 mg/kg
  Mg: ≤0.1 mg/kg
  Mn: ≤0.02 mg/kg
  Mo: ≤0.1 mg/kg
  Na: ≤0.5 mg/kg
  Ni: ≤0.02 mg/kg
  Pb: ≤0.1 mg/kg
  Sn: ≤0.1 mg/kg
  Sr: ≤0.1 mg/kg
  Zn: ≤0.1 mg/kg
SMILES string C1CCOC1
InChI 1S/C4H8O/c1-2-4-5-3-1/h1-4H2
InChI key WYURNTSHIVDZCO-UHFFFAOYSA-N

General description

The product is tetrahydrofuran (THF) and it contains 250ppm BHT (Butylated hydroxytoluene) as an inhibitor. THF is widely employed as a solvent. It constitutes the key fragment of various natural products (polyether antibiotics). THF forms double hydrate with hydrogen sulfide. Crystal structure of this double hydrate has been investigated by three-dimensional single-crystal studies. Butane-1,4-diol is formed as an intermediate during the synthesis of THF. Hot THF is useful for the dissolution of polyvinylidene chloride (PVDV).

Application

Tetrahydrofuran has been used as a solvent for the preparation of sol-gel solution for coating solid phase microextraction (SPME) fibers in a study.

It may be used for the dissolution of poly-ε-caprolactone (PCL) and 1,3-diaminopentane, during the preparation of poly-ε-caprolactone (PCL)-hydroxyapatite (HA) scaffolds and acrylate-terminated poly(5-amino-1-pentanol-co-1,4-butanediol diacrylate) (C32)- 1,3-diaminopentane (117) polymer, respectively.

Analysis Note

miscible with water and ethanol (96%) pass

Other Notes

GHS02, GHS07, GHS08

Signal word Danger
Hazard statements H225-H302-H319-H335-H351
Precautionary statements P210-P280-P301 + P312 + P330-P305 + P351 + P338-P370 + P378-P403 + P235
Supplemental Hazard Statements May form explosive peroxides.
RIDADR UN 2056 3 / PGII
WGK Germany 1
RTECS LU5950000
Flash Point(F) 1.4 °F
Flash Point(C) -17 °C

Documents 

Warnings

Note: These chemicals are for research & laboratory use only. Your order will not be processed if you do not work for, and ship to, a registered laboratory or research facility. Not for topical applications. An official Declaration of Use form may be required.

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WARNING: This product can expose you to chemicals which are known to the State of California to cause cancer and reproductive harm. Prop 65 Warning

Please note: This product is not returnable.

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MPN:
87368-1L