Sigma-Aldrich

Diethylene Glycol Dimethyl Ether Reagent Plus® 99%, 500 mL

Part Number:
MIL-M14102-500ML
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2-4 weeks
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Size:
500 ml / 16 ounce
Style:
chemical
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Price: $186.15

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Description

Diethylene Glycol Dimethyl Ether Reagentplus 99% 500mL

Synonym:‘Diglyme’, 2-Methoxyethyl ether, Bis(2-methoxyethyl) ether, Dimethyldiglycol

  • CAS Number 111-96-6
  • Linear Formula (CH3OCH2CH2)2O
  • Molecular Weight 134.17
  • Beilstein/REAXYS Number 1736101
  • EC Number 203-924-4
  • MDL number MFCD00008503
  • PubChem Substance ID 329817875
  • NACRES NA.21
grade ReagentPlus®
vapor density 4.6 (vs air)
vapor pressure 3 mmHg ( 20 °C)
assay 99%
autoignition temp. 370 °F
expl. lim. 17.4 %
color APHA: ≤10
refractive index n20/D 1.408 (lit.)
bp 162 °C (lit.)
mp −64 °C (lit.)
density 0.944 g/mL at 20 °C (lit.)
  0.939 g/mL at 25 °C (lit.)
SMILES string COCCOCCOC
InChI 1S/C6H14O3/c1-7-3-5-9-6-4-8-2/h3-6H2,1-2H3
InChI key SBZXBUIDTXKZTM-UHFFFAOYSA-N

General description

Diethylene glycol dimethyl ether (diglyme), a hydrophilic ether, is an electron-donor solvent. Its toxicity has been assessed. The effect of complexation of diglyme with lithium trifluoromethanesulfonate on the conformation has been investigated. It is reported to enhance the ability of KF-MeOH-Al2O3 (potassium fluoride-methanol-alumina) reagent to replace halogen with methoxy groups in 5,8-dihydroxy-2,3-dichloro-1,4-naphthoquinones.

Application

Diethylene glycol dimethyl ether may be used as a solvent to form a solution of sodium pentaphosphacyclopentadienide.

GHS02, GHS08

Signal word Danger
Hazard statements H226-H360
Precautionary statements P201-P210-P280-P308 + P313-P370 + P378
Supplemental Hazard Statements May form explosive peroxides.
RIDADR UN 3271 3 / PGIII
WGK Germany 1
RTECS KN3339000
Flash Point(F) 134.6 °F
Flash Point(C) 57 °C

Documents 

Warnings

Note: These chemicals are for research & laboratory use only. Your order will not be processed if you do not work for, and ship to, a registered laboratory or research facility. Not for topical applications. An official Declaration of Use form may be required.

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WARNING: This product can expose you to chemicals which are known to the State of California to cause cancer and reproductive harm. Prop 65 Warning

Please note: This product is not returnable.

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MPN:
M14102-500ML