Sigma-Aldrich

Carbon Disulfide 99.9%+, ACS Reagent, 2 Liter

Part Number:
MIL-180173-2L
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2-4 weeks
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1 unit
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2000 ml / 64 ounce
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MSRP: $228.00
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Description

Carbon Disulfide >/=99.9% ACS Reagent & 2 Liter

  • CAS Number 75-15-0
  • Empirical Formula (Hill Notation) CS2
  • Molecular Weight 76.14
  • Beilstein/REAXYS Number 1098293
  • EC Number 200-843-6
  • MDL number MFCD00011321
  • PubChem Substance ID 329751607
Grade ACS reagent
Vapor Density 2.67 (vs air)
Vapor Pressure 5.83 psi
InChI Key QGJOPFRUJISHPQ-UHFFFAOYSA-N
Assay ≥99.9%
Autoignition Temperature 212°F
expl. lim. 50 %
Impurities

H2S, passes test (lim. ~1.5 ppm)

SO2, passes test (lim ~2.5 ppm)

≤0.05% water

evapn. residue ≤0.002%
Color APHA: ≤10
Refractive Index n20/D 1.627 (lit.)
bp 46°C (lit.)
mp −112-−111°C (lit.)
Density

1.266 g/mL at 25°C (lit.)

General description

Carbon disulfide (CS2) is a colorless liquid. It is present in atmosphere and natural waters in the form of sulfur gas. It is responsible for the production of sulfur dioxide (SO2) in the atmosphere (stratosphere and/or troposphere). Its lifetime in the atmosphere has been proposed to be around 12 days. It is a non-polar solvent.

Carbon disulfide is a highly volatile, flammable liquid with low ignition temperature. It can be synthesized by reacting hydrocarbon gas with sulfur. It is an important raw material for preparing viscose rayon and cellophane film.

Application

Carbon disulfide has been used for the desorption of air samples during analysis of trihalomethanes (THMs) in those samples.
It may be used in the preparation of dibenzyl trithiocarbonate, a RAFT (Reversible Addition-Fragmentation Transfer) chain-transfer agent (CTA). It may be employed as a solvent in the preparation of benzyl chlorodithioformate.

Carbon disulfide may be used in the xanthogenation of cellulose and in the synthesis of poly(ethylene trithiocarbonate) and dithiocarbamates. C2S may undergo hydrolysis catalyzed by nanosized titania and zirconia to form CO2 and H2S. It can also generate 1,3-dithiolium carbenes via cycloaddition with acetylenes.

Safety Information

GHS02GHS07GHS08GHS02,GHS07,GHS08

Signal word Danger

Hazard statements H225-H315-H319-H332-H361fd-H372
Precautionary statements P210-P260-P280-P305 + P351 + P338-P370 + P378-P403 + P235
RIDADR UN1131 - class 3 - PG 1 - Carbon disulfide
WGK Germany 2
RTECS FF6650000
Flash Point(F) -22°F
Flash Point(C) -30°C

Documents

Safety Data Sheet

Warnings

Note: These chemicals are for research & laboratory use only. Your order will not be processed if you do not work for, and ship to, a registered laboratory or research facility. Not for topical applications. An official Declaration of Use form may be required.

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WARNING: This product can expose you to chemicals which are known to the State of California to cause cancer and reproductive harm. Prop 65 Warning

Please note: This product is not returnable.

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MPN:
180173-2L