Sigma-Aldrich

Chloroform For HPLC 99.8%+ Amylene Stabilized, 4 Liter, case/4

Part Number:
MIL-34854-4X4L
Lead Time:
2-4 weeks
Minimum Purchase:
1 unit
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Quantity:
4
Size:
4 liter / 1 gallon
Style:
chemical
DOT Rated:
HazMat Transport Fee Required
Price: $803.62

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Description

Chloroform For HPLC ≥99.8% Amylene Stabilized 4 Liter Case/4

Synonym: Methylidyne trichloride, Trichloromethane

  • CAS Number 67-66-3
  • Empirical Formula (Hill Notation) CHCl3
  • Molecular Weight 119.38
  • Beilstein/REAXYS Number 1731042
  • EC Number 200-663-8
  • MDL number MFCD00000826
  • PubChem Substance ID 329755063
  • NACRES NA.04
Grade for HPLC
Vapor Density 4.1 (vs air)
Vapor Pressure 160 mmHg (20°C)
Assay ≥99.8%
quality amylene stabilized
Impurities

Free acid, in accordance
acetone, aldehyde, in accordance (nessler test)
free chlorine (Cl), in accordance
≤0.0005% non-volatile matter
≤0.001% free acid (as HCl)
<0.01% water (Karl Fischer)

Evaporation Residue ≤0.0005%
Color APHA: ≤10
transmittance

250 Nm, ≥50%
260 Nm, ≥85%
280 Nm, ≥99%

Refractive Index n20/D 1.445 (lit.)
bp 60.5-61.5°C (lit.)
mp −63°C (lit.)
Density

1.48 G/mL At 25°C
1.492 G/mL At 25°C (lit.)

anion traces chloride (Cl-): in accordance
cation traces Pb: ≤0.05 mg/kg
absorption in accordance
λ H2O reference
UV absorption

λ: 250 Nm Amax: ≤1.00
λ: 260 Nm Amax: ≤0.30
λ: 280 Nm Amax: ≤0.005

suitability

passes test for reaction against H2SO4
passes test for suitability of determ. w. dithizone

Featured Industry Food and Beverages

General description
Chloroform, a halogenated hydrocarbon, is widely employed as a solvent. Its photochemical degradation has been investigated in the presence of TiO2 aqueous suspensions (wavelength range of 310-380nm).

Application
Chloroform has been employed for the ion exchange isolation of sulfatides from the urinary samples by using DEAE-cellulose membranes before the tandem mass spectrometric analysis. It has been used as a solvent for the Langmuir-Blodgett (LB) deposition of lipid bilayers over mica sheets (silver coated back).

Safety Information

Signal word Danger
Hazard statements H302-H315-H319-H331-H336-H351-H361d-H372
Precautionary statements P201-P260-P264-P280-P304 + P340 + P312-P403 + P233
RIDADR UN 1888 6.1 / PGIII
WGK Germany 3
RTECS FS9100000

Documents 

Warnings

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WARNING: This product can expose you to chemicals which are known to the State of California to cause cancer and reproductive harm. Prop 65 Warning

Please note: This product is not returnable.

General description Cyclohexane undergoes oxidation in the presence of various oxidants such as hydrogen peroxide, tert-butyl hydroperoxide and molecular oxygen.[2]
Application Cyclohexane has been used to prepare a 1.3M solution of sec-butyllithium.[3] It may be used as a starting Reagent for the synthesis of adipic acid[1] and ε-caprolactam.[1]

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MPN:
34854-4X4L