Sigma-Aldrich

Sodium Methoxide 25 Wt.%, Solution 18 Liter

Part Number:
MIL-156256-18L
Lead Time:
2-4 weeks
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Size:
18 liter
Style:
chemical
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Price: $829.00

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Description

Sodium Methoxide 25 Wt. % Solution 18 Liter

Synonym: Sodium methylate

  • CAS Number 124-41-4
  • Linear Formula CH3ONa
  • Molecular Weight 54.02
  • Beilstein/REAXYS Number 3592982
  • MDL number MFCD00012179
  • PubChem Substance ID 24849600
Vapor Density 1.1 (vs air)
Vapor Pressure

50 mmHg (20°C)
96 mmHg (25°C)
InChI Key WQDUMFSSJAZKTM-UHFFFAOYSA-N
Autoignition Temperature 878°F
concentration 25 wt. % in methanol
Refractive Index n20/D 1.37
Density 0.945 g/mL at 25°C


General description

The product is 25 wt.% solution of sodium methoxide in methanol. Its reaction with unactivated aryl bromides in the presence of copper catalyst under various reaction conditions has been studied. It reacts with aryl halides in the presence of a palladium catalyst in DMF (Dimethylformamide) to afford arenes.

Application

A novel high-spin hexanuclear Mn(III) cluster, [NaMn6(OMe)12(dbm)6]+, was synthesized via MnCl2 oxidation with simultaneous NaOMe promoted aggregation. This cluster has an unprecedented cyclic structure and 24 unpaired electrons in its ground state.

Sodium methoxide solution has been used in the synthesis of NO-containing nanoparticles (SNO-NP).

Safety Information

GHS02GHS05GHS06GHS08  GHS02, GHS05, GHS06, GHS08

Signal word Danger
Hazard statements H225-H251-H301 + H311 + H331-H314-H370
Precautionary statements P210-P235 + P410-P260-P280-P301 + P310-P305 + P351 + P338
Supplemental Hazard Statements Reacts violently with water.
RIDADR UN1289 - class 3 - PG 2 - Sodium methylate solutions
WGK Germany 1
Flash Point(F) 51.8°F
Flash Point(C) 11°C


Documents

Safety Data Sheet

Warnings

Note: These chemicals are for research & laboratory use only. Your order will not be processed if you do not work for, and ship to, a registered laboratory or research facility. Not for topical applications. An official Declaration of Use form may be required.

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WARNING: This product can expose you to chemicals which are known to the State of California to cause cancer and reproductive harm. Prop 65 Warning

Please note: This product is not returnable.

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MPN:
156256-18L